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Lecturer(s)
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Polášková Martina, doc. Ing. Ph.D.
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Course content
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1. Macromolecules, molecular weight and its distribution, influence of molecular weight on physical properties of polymer. 2. Chemical bonds, intermolecular interactions, cohesion energy and shape of molecules. 3. Molecular structure of polymers, configuration of polymer chain and steric isomerism, conformation of polymers. 4. Supramolecular structure - polymer morphology, crystallization, crystal transformations. 5.Thermal behaviour of polymers, glass transition temperature, effect of molecular structure on glass transition temperature, effect of molecular structure on melting temperature. 6. Polymer solutions, good and bad solvents, solutions of high molecular weight electrolytes, miscibility of two polymers, morphology of immiscible mixtures. 7. Synthesis of macromolecules, functionality, polycondensation a polyaddition. 8. Chain polymerization reaction, radical polymerization, inhibition, retardation. 9. Copolymerization, methods of performing radical polymerisations and copolymerisations. 10. Ionic polymerization - cationic polymerization, anionic polymerization and complex coordination polymerization. 11. Enzymatic synthesis of biopolymers, proteins, polysaccharides, rubbers, polynucleotides. 12. Synthesis of graft and block copolymers. 13. Polymer chain reactions, intramolecular reactions, intermolecular reactions. 14. Destructive reaction of polymers, thermo-oxidative destruction, mechanical degradation, photo-oxidative destruction, chemical and enzymatic destruction.
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Learning activities and teaching methods
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Dialogic (Discussion, conversation, brainstorming)
- Preparation for examination
- 50 hours per semester
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| teaching methods |
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| Knowledge |
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| Individual work of students |
| Individual work of students |
| Skills |
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| Individual work of students |
| Individual work of students |
| assessment methods |
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| Knowledge |
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| Oral examination |
| Oral examination |
| Grade (Using a grade system) |
| Grade (Using a grade system) |
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Recommended literature
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Malcom P. Stevens. Polymer Chemistry - An Introduction. New York, 1999. ISBN 0-19-512444-8.
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Mleziva, J. Polymery - struktura,vlastnosti a použití. Praha : Sobotáles, 1993.
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Rybnikář, F. Makromolekulární chemie I. Brno : VUT, 1988.
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Zámorský, Z. Nauka o polymerech I. Brno : VUT, 1982.
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Zámorský, Z. Nauka o polymerech II. Brno : VUT, 1985.
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