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Lecturer(s)
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Smolková Ilona, MSc. PhD.
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Kočí Kamila, prof. Ing. Ph.D.
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Course content
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- Chemical kinetics - rate of reaction, rate equations, rate constant, order and molecularity of reaction. - Formal kinetics of first and second order reactions, fractional reaction time, determination of reaction order and rate constant. - Temperature dependence of reaction rate, Arrhenius equation, collision theory, activated complex theory. - Simultaneous reaction systems, reversible, successive and lateral reactions, stationary state approximation. - Homogeneous and heterogeneous catalysis - principle and selected kinetic models. - Adsorption on solid phase, Langmuir and Freundlich isotherms. - Electrochemistry - current conduction in electrolytes, specific and molar conductivity, ion mobility, conversion numbers. - Theory of acids and bases, dissociation constant, calculations of pH and composition of solution, ampholytes, isoelectric point. - Thermodynamics of electrolytes, mean activity coefficient, electrochemical cells, Nernst equation, electrode potentials, redox reactions. - Electrolysis, Faraday's laws, polarization of electrodes, polarography. - Colloidal systems and their classification, kinetic properties, coagulation. - Macromolecules in solution, random ball, radius of gyration, distribution function, mean size and molecular weight. - Methods of molecular weight determination - osmometry, sedimentation, light scattering, viscometry. - Thermodynamics of polymer solutions, lattice theory, phase equilibria in polymer solutions, fractionation.
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Learning activities and teaching methods
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Lecturing, Simple experiments, Practice exercises
- Preparation for examination
- 180 hours per semester
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| prerequisite |
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| Knowledge |
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| Knowledge of mathematics, physics and inorganic, organic and analytical chemistry. |
| Knowledge of mathematics, physics and inorganic, organic and analytical chemistry. |
| learning outcomes |
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| analyse the kinetics of chemical reactions |
| analyse the kinetics of chemical reactions |
| discuss the theory of acids and bases |
| discuss the theory of acids and bases |
| explain the catalysis of chemical reactions |
| explain the catalysis of chemical reactions |
| explain the thermodynamics of solutions |
| explain the thermodynamics of solutions |
| discuss the issue of electrochemical cells |
| discuss the issue of electrochemical cells |
| Skills |
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| quantify and describe the investigated phenomena by physical relations |
| quantify and describe the investigated phenomena by physical relations |
| apply the Langmuir and Freundlich isotherms |
| apply the Langmuir and Freundlich isotherms |
| apply the Nernst equation |
| apply the Nernst equation |
| calculate the temperature dependence of the reaction rate |
| calculate the temperature dependence of the reaction rate |
| calculate the pH of solutions |
| calculate the pH of solutions |
| determine the molecular weight |
| determine the molecular weight |
| teaching methods |
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| Knowledge |
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| Lecturing |
| Lecturing |
| Dialogic (Discussion, conversation, brainstorming) |
| Dialogic (Discussion, conversation, brainstorming) |
| Skills |
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| Simple experiments |
| Simple experiments |
| Practice exercises |
| Practice exercises |
| assessment methods |
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| Knowledge |
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| Systematic observation of the student |
| Systematic observation of the student |
| Written examination |
| Written examination |
| Oral examination |
| Oral examination |
| Grade (Using a grade system) |
| Grade (Using a grade system) |
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Recommended literature
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ATKINS, P., DE PAULA, J. Atkins´physical chemistry. 8th ed.. Oxford University Press, Oxford, 2006. ISBN 9780198700722.
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ATKINS, P., DE PAULA, J. Fyzikální chemie. VŠCHT, Praha, 2013. ISBN 978-80-7080-830-6.
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FINK, J.C. Physical Chemistry in Depth. Springer, Heidelberg, 2009.
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KUHN, H., FÖRSTERLING, H.-D., WALDECK, D.H. Principles of Physical Chemistry. Wiley, New Jersey, 2009.
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NOVÁK, J. a kol. Fyzikální chemie ? bakalářský a magisterský kurz. VŠCHT, Praha, 2008. ISBN 978-80-7080-675-3.
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Novák J. a kol. Příklady a úlohy z fyzikální chemie. VŠCHT Praha, 2000. ISBN 80-7080-394-0.
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