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Lecturer(s)
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Halouzka Vladimír, Mgr. Ph.D.
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Ingr Marek, doc. RNDr. Ph.D.
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Course content
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1. Perfect gas, gas laws, equation of state, equipartition principle, real gases, van der Waals equation, compressibility factor, virial expansion, critical point, state behaviour of liquids. 2. Thermodynamics, state variables, work, heat, energy. 3. First law of thermodynamics, internal energy, enthalpy, heat capacities, adiabatic process. 4. Heat of reaction, calorimetry, heat to work transformation, Carnot cycle, heat engines. 5. Second law of thermodynamics, entropy, third law of thermodynamics, inversion temperature. 6. Combination of the first and second law the thermodynamics, Helmholtz and Gibbs energies, conditions of thermodynamical equilibrium. 7. Surface tension, viscosity of liquids, amorphous and crystalline substances, elements of crystallography. 8. Phase equilibrium, Clapeyron and Claussius - Clapeyron equations. 9. Multicomponent systems, chemical potential, fugacity, Gibbs phase rule. 10. Equilibrium liquid - gas, ideal solution, Raoult law, Henry law. 11. Real systems, activity, activity coefficient, azeotropic mixture. 12. Equilibrium liquid - liquid, limited miscibility, upper and lower critical temperatures. 13. Condensed systems, phase diagrams, eutectics, three components systems. 14. Chemical equilibrium, equilibrium constant, Gibbs free energy, equilibrium composition of reaction mixture, temperature and pressure influence on chemical equilibrium, Le-Chatelier-Brown principle.
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Learning activities and teaching methods
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Lecturing, Simple experiments, Practice exercises
- Participation in classes
- 24 hours per semester
- Home preparation for classes
- 56 hours per semester
- Preparation for course credit
- 50 hours per semester
- Preparation for examination
- 50 hours per semester
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| prerequisite |
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| Knowledge |
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| Knowledge of mathematics, physics and inorganic, organic and analytical chemistry. |
| Knowledge of mathematics, physics and inorganic, organic and analytical chemistry. |
| learning outcomes |
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| describe the properties and behaviour of an ideal gas |
| describe the properties and behaviour of an ideal gas |
| explain the laws of thermodynamics |
| explain the laws of thermodynamics |
| describe states of matter |
| describe states of matter |
| explain the catalysis of chemical reactions |
| explain the catalysis of chemical reactions |
| describe chemical equilibrium |
| describe chemical equilibrium |
| Skills |
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| quantify and describe the investigated phenomena by physical relations |
| quantify and describe the investigated phenomena by physical relations |
| calculate the state variables of an ideal gas |
| calculate the state variables of an ideal gas |
| apply the laws of thermodynamics |
| apply the laws of thermodynamics |
| calculate equilibrium constants of chemical reactions |
| calculate equilibrium constants of chemical reactions |
| distinguish states of matter |
| distinguish states of matter |
| teaching methods |
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| Knowledge |
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| Lecturing |
| Lecturing |
| Dialogic (Discussion, conversation, brainstorming) |
| Dialogic (Discussion, conversation, brainstorming) |
| Skills |
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| Simple experiments |
| Simple experiments |
| Practice exercises |
| Practice exercises |
| assessment methods |
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| Knowledge |
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| Preparation of a presentation |
| Preparation of a presentation |
| Systematic observation of the student |
| Systematic observation of the student |
| Written examination |
| Written examination |
| Oral examination |
| Oral examination |
| Grade (Using a grade system) |
| Grade (Using a grade system) |
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Recommended literature
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Adamcová, Z. Příklady a úlohy z fyzikální chemie. Praha : SNTL, 1989.
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Atkins P., De Paula J. Fyzikální chemie. Praha, 2013. ISBN 9788070808306.
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Atkins, P. W. Atkins´physical chemistry. 7th ed. New York : Oxford University Press, 2002. ISBN 198792859.
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Erdos, E., Pick, J., Černý, Č., Pouchlý, J. Fyzikální chemie v otázkách I, II, III. Praha : Academia, 1975.
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Moore, W.J. Fyzikální chemie. SNTL Praha, 1979.
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Novák J. a kol. Příklady a úlohy z fyzikální chemie. Praha, 2000. ISBN 80-7080-394-0.
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Novák, J. Fyzikální chemie - bakalářský a magisterský kurz. Praha, 2008. ISBN 978-80-7080-675-.
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Novák, J. P., Pick, J., Holub, R. Fyzikální chemie. Praha : VŠCHT, 1999. ISBN 80-7080-360-6.
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Šimek, L., Hrnčiřík, J. Fyzikální chemie II : Koloidní a makromolekulární systémy. Zlín : UTB, 2005. ISBN 80-7318-325-0.
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Šimek, L., Hrnčiřík, J. Fyzikální chemie I. UTB Zlín , 2007. ISBN 978-80-7318-324-0.
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