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Lecturer(s)
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Barbuščáková Zuzana, Mgr.
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Janovský Petr, Ing. Ph.D.
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Kimmel Roman, Ing. Ph.D.
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Kovář Michal, Ing.
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Prucková Zdeňka, Ing. Ph.D.
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Course content
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1. Nomenclature system of organic compounds. 2. Configuration of R and S, E and Z, cis and trans, perspective formulas, Fisher's formulas. 3. Radical substitutions of alkanes and cycloalkanes, mechanisms, stability of radicals. 4. Alkenes and cycloalkenes - ionic additions, radical additions, radical substitutions. 5. Oxidation of alkenes, Diels-Alder reactions. 6. Acidity of alkynes, addition to triple bond. 7. Electrophilic aromatic substitution of benzene, electrophilic aromatic substitution of substituted benzene and naphthalene (regioselectivity and rate). 8. Nucleophilic substitution of halogen derivatives, elimination of halogen derivatives (dehydrohalogenation and dehalogenation), nucleophilic aromatic substitution of activated halogen. 9. Reactions of halogen derivatives with metals (Na, Li, Mg), reactions of lithium and magnesium organometals with "acidic hydrogen", addition of organometals. 10. Acidity and alkalinity of alcohols, substitution, dehydration of alcohols, oxidation of alcohols; ethers - alkalinity, cleavage. 11. Reduction of aromatic nitro compounds; basicity of amines - protonation and reaction with Lewis acids (with halogen derivatives and nitrosyl cation, diazotation). 12. Reactions of aromatic diazonium salts, coupling. 13. Reactions of aldehydes and ketones. 14. Ester (Claisen) condensation.
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Learning activities and teaching methods
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Dialogic (Discussion, conversation, brainstorming), Practice exercises
- Participation in classes
- 28 hours per semester
- Home preparation for classes
- 20 hours per semester
- Preparation for course credit
- 12 hours per semester
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| prerequisite |
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| Knowledge |
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| Basic knowledge of chemistry - at secondary school level. |
| Basic knowledge of chemistry - at secondary school level. |
| learning outcomes |
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| The student has knowledge of the basics of reactivity and structure of organic molecules. |
| The student has knowledge of the basics of reactivity and structure of organic molecules. |
| He/she masters the basics of nomenclature of the most important groups of organic compounds. |
| He/she masters the basics of nomenclature of the most important groups of organic compounds. |
| Skills |
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| Student dovede předpovědět reaktivitu základních skupin organických sloučenin. |
| Student dovede předpovědět reaktivitu základních skupin organických sloučenin. |
| The student can predict the reactivity of basic groups of organic compounds. |
| The student can predict the reactivity of basic groups of organic compounds. |
| teaching methods |
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| Knowledge |
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| Dialogic (Discussion, conversation, brainstorming) |
| Dialogic (Discussion, conversation, brainstorming) |
| Skills |
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| Practice exercises |
| Practice exercises |
| assessment methods |
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| Knowledge |
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| Systematic observation of the student |
| Systematic observation of the student |
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Recommended literature
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Fikr, Jaroslav. Názvosloví organické chemie. 1. vyd. Olomouc : Rubico, 2002. ISBN 8085839717.
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Hrnčiar, P. Organická chémia. Bratislava : SPN, 1990. ISBN 80-08-00028-7.
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Kolektiv. Chemie organických sloučenin I a II. Praha : SNTL, 1985.
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McMurry, J. Organická chemie. Brno: VUTIUM, 2007.
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Panico, R., Powel, W. H., Richter, J.-C. Průvodce názvoslovím organických sloučenin podle IUPAC -doporučení 1993. Praha : Academia, 2000. ISBN 80-200-0724-5.
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Solomons, Graham T.W. Organic chemistry. New York : John Wiley, 1996. ISBN 0-471-01342-0.
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