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Lecturer(s)
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Kočí Kamila, prof. Ing. Ph.D.
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Kolaříková Alena, Ing.
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Smolková Ilona, MSc. PhD.
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Václavková Tereza, Ing. Ph.D.
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Course content
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1. Ideal gas, laws of gases, equation of state, equipartition principle, real gases, van der Waals equation, compressibility factor, virial development, critical point, state behavior of liquids. 2. Thermodynamics, state variables, work, heat, energy. 3. I. law of thermodynamics, internal energy, enthalpy, heat capacities, adiabatic process. 4. Reaction heat, calorimetry, heat conversion to work, Carnot cycle, heat engines. 5. II. thermodynamic law, entropy, III. thermodynamic law, inverse temperature. 6. Connections I. and II. law of thermodynamics, Helmholtz and Gibbs energy, conditions of thermodynamic equilibrium. 7. Surface tension, viscosity of liquids, crystalline, amorphous substances, basics of crystallography. 8. Phase equilibria, Clapeyron and Claussius -Clapeyron equations. 9. Multicomponent systems, chemical potential, fugacity, Gibbs law of phases. 10. Equilibrium liquid-vapor, ideal solution, Raoult's law, Henry's law. 11. Real systems, activity, activity coefficient, azeotropic mixture. 12. Liquid-liquid equilibrium, limited miscibility, upper and lower critical temperature. 13. Condensed systems, phase diagrams, eutectic, three-component system. 14. Chemical equilibria, equilibrium constant, reaction Gibbs energy, equilibrium composition of reaction mixture, influence of temperature and pressure on chemical equilibrium, Le-Chatelier-Brown principle.
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Learning activities and teaching methods
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Lecturing, Simple experiments, Practice exercises
- Participation in classes
- 84 hours per semester
- Home preparation for classes
- 40 hours per semester
- Preparation for course credit
- 20 hours per semester
- Preparation for examination
- 36 hours per semester
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| prerequisite |
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| Knowledge |
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| Knowledge of mathematics, physics and inorganic, organic and analytical chemistry. |
| Knowledge of mathematics, physics and inorganic, organic and analytical chemistry. |
| learning outcomes |
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| describe the properties and behaviour of an ideal gas |
| describe the properties and behaviour of an ideal gas |
| explain the laws of thermodynamics |
| explain the laws of thermodynamics |
| describe states of matter |
| describe states of matter |
| explain the catalysis of chemical reactions |
| explain the catalysis of chemical reactions |
| describe chemical equilibrium |
| describe chemical equilibrium |
| Skills |
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| quantify and describe the investigated phenomena by physical relations |
| quantify and describe the investigated phenomena by physical relations |
| calculate the state variables of an ideal gas |
| calculate the state variables of an ideal gas |
| apply the laws of thermodynamics |
| apply the laws of thermodynamics |
| calculate equilibrium constants of chemical reactions |
| calculate equilibrium constants of chemical reactions |
| distinguish states of matter |
| distinguish states of matter |
| teaching methods |
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| Knowledge |
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| Lecturing |
| Lecturing |
| Dialogic (Discussion, conversation, brainstorming) |
| Dialogic (Discussion, conversation, brainstorming) |
| Skills |
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| Simple experiments |
| Simple experiments |
| Practice exercises |
| Practice exercises |
| assessment methods |
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| Knowledge |
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| Systematic observation of the student |
| Systematic observation of the student |
| Written examination |
| Written examination |
| Oral examination |
| Oral examination |
| Grade (Using a grade system) |
| Grade (Using a grade system) |
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Recommended literature
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Adamcová, Z. Příklady a úlohy z fyzikální chemie. Praha : SNTL, 1989.
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Atkins, P. W. Atkins´physical chemistry. 7th ed. New York : Oxford University Press, 2002. ISBN 198792859.
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Erdos, E., Pick, J., Černý, Č., Pouchlý, J. Fyzikální chemie v otázkách I, II, III. Praha : Academia, 1975.
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Moore, W.J. Fyzikální chemie. SNTL Praha, 1979.
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Novák J. a kol. Příklady a úlohy z fyzikální chemie. Praha, 2000. ISBN 80-7080-394-0.
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Novák, J. P., Pick, J., Holub, R. Fyzikální chemie. Praha : VŠCHT, 1999. ISBN 80-7080-360-6.
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